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Jeff Masters has a detailed analysis of heat records around the world: “Hottest air temperatures reported on Earth.”
Conclusion: Death Valley has the hottest verified records, but much of Africa is not monitored by properly sited instruments.
Get this book for a peek at the best online science writing going on right now. It is a selection of science articles from 2011, but even if a few years have passed, the writing is still excellent and the articles are still important.